期刊
ELECTROCHIMICA ACTA
卷 260, 期 -, 页码 965-973出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2017.12.078
关键词
Fe3O4; Porous carbon matrix; Graphene; Anode; Lithium ion batteries
资金
- NTU-JM joint project [M4061392]
- Tier 1 (AcRF grant MOE Singapore) [M401992]
- Tier 2 (AcRF grant MOE Singapore) [M4020159]
- Chinese Natural Science Foundation [51271031, 50701006]
- National Basic Research Program [2014CB6433000]
In the present paper, the hierarchical three-dimensional Fe3O4@porous carbon matrix (PCM) and Fe3O4@PCM/graphene are synthesized by a facile annealing of Mil-53(Fe) templates. Their electrochemical performances are evaluated as anode materials for lithium ion batteries. In comparison with Fe3O4@PCM, the Fe3O4@PCM/graphene electrode exhibits a much better cycling performance with the reversible capacity high up to 1000 mAh g(-1) after 500 cycles at 1 C. The improved performance can be ascribed to the high conductivity and structure stability provided by the unique graphene based hierarchical three-dimensional nanostructure. (c) 2017 Elsevier Ltd. All rights reserved.
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