期刊
ELECTROCHIMICA ACTA
卷 274, 期 -, 页码 200-207出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2018.04.063
关键词
Supercapacitors; Hierarchical structures; Polyaniline; Polypyrrole
资金
- FINEP
- CAPES
- FAPESB
- FACEPE
- CNPq
Developing low-cost and efficient flexible supercapacitors is an important step towards the production of new energy storage systems for efficient wearable electronic devices. In this work, we report a simple and cost-effective approach to produce flexible electrodes for supercapacitors. The system consists of a complex ternary structure of hierarchical polyaniline (PAn) assembled on a polypyrrole (PPy) layer deposited on graphite pencil traces (Grt) in sandpaper. The proposed ternary composite PAn-PPy-Grt-Sp assembled in a device offered a maximal areal capacitance of 55.35 mF cm(-2) at 0.3 mA cm(-2), a higher value when compared to its counterparts of PAn-Grt-Sp (31.8 mF cm(-2)) and PPy-Grt-Sp (19.75 mF cm(-2)). The ternary composite also exhibited a higher energy (4.92 mu Wh cm(-2)) and power density (87.09 mu Wcm(-2)) at a current density of 0.3 mA cm(-2) producing a more equilibrated supercapacitor device. The response to mechanical efforts returned negligible variation in electrochemical properties while cyclability remains as 80% of initial value after 3000 cycles. (c) 2018 Elsevier Ltd. All rights reserved.
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