期刊
ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY
卷 159, 期 -, 页码 332-341出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.ecoenv.2018.05.015
关键词
Layered double hydroxide; Mesoporous triple-metal nanosorbent; Reactive Blue 19; Kinetics; Isotherms; Wastewater
资金
- Ministry of Education, Science and Technological Development of the Republic of Serbia [TR 34008]
In this study, co-precipitation synthesis of the mesoporous triple-metal nanosorbent from Fe, Cu, Ni layered double hydroxide (FeCuNi-LDH), on the basis of the data obtained from the TG analysis was carried out. The FTIR spectroscopy and XRD results confirm the formation of CuO, NiO and Fe2O3 nanoparticles, while the EDX analysis does not show significant variations on the surface in elemental composition. BET analysis shows that FeCuNi-280 (FeCuNi-LDH calcinated at 280 degrees C) with mesoporous structure, has larger surface area compared to FeCuNi-LDH and FeCuNi-550 (FeCuNi-LDH calcinated at 550 degrees C). The value of pH(PZC) of FeCuNi-280 is found to be 8.66. Obtained FeCuNi-280 material showed the ability for efficient removal of dye Reactive Blue 19 (RB19) from water, with a very high sorption capacity of 480.79 mg/g at optimal conditions: the sorbent dose of 0.6 g/dm(3), stirring speed of 280 rpm and pH 2. The kinetics results of the sorption process were well fitted by pseudo second order and Chrastil model, and the sorption isotherm was well described by Sips, Langmuir and Brouers-Sotolongo model. FeCuNi-280 was easily regenerated with aqueous solution of NaOH, and reutilization was successfully done in five sorption cycles. The present study show that easy-to-prepare, relatively inexpensive nanosorbent FeCuNi-280 is among the best sorbents for the removal of RB19 dye from water solution and wastewater from textile industry in wide range of pH.
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