期刊
DYES AND PIGMENTS
卷 152, 期 -, 页码 54-59出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.dyepig.2018.01.036
关键词
Gold(I) complex; Bipyridine; Aggregation-induced phosphorescent emission; Mechanochromism; Self-assembly
资金
- National Natural Science Foundation of China [21702079, 21472059, 21662015]
- Project of Jiangxi Sci-Tech Innovative Team [20142BCB24012]
- 5511 Science and Technology Innovation Talent Project of Jiangxi Province [20165BCB18015]
- Project of Jiangxi Academic and Technological leader [20142BCB22010]
- key project of Natural Science Foundation of Jiangxi Province [20171ACB20025]
- youth project of Natural Science Foundation of Jiangxi Province [20171BAB213004]
- Young Talents Project of Jiangxi Science and Technology Normal University [2017QNBJRC005]
- Project of the Science Fund of Jiangxi Education Office [GJJ160764]
Mechanochromic luminescent materials have received a great deal of attention due to their potential applications in sensors and optoelectronic devices. Meanwhile, the aggregation-induced emission active materials commonly exhibit bright luminescence upon aggregate formation, which is extremely important for preparation of high-contrast mechanochromism materials. On the other hand, it is well-known that pyridine-type ligands are one of the most versatile ligands. Unfortunately, the number of pyridine gold complexes is quite limited, not to mention pyridine-containing gold(I) complexes with aggregation-induced emission or mechanochromic phenomenon. In this work, a new bipyridine-based aggregation-induced phosphorescent emission active gold(I) complex is reported. The novel luminogen exhibits reversible mechanochromism phenomenon with phosphorescent changes between weak green and strong yellow emissions. Moreover, the luminogen shows a significative self-assembly behavior. This work will be beneficial for the exploitation of force-responsive phosphorescent sensor materials with remarkable self-assembly behavior.
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