期刊
DALTON TRANSACTIONS
卷 47, 期 26, 页码 8817-8823出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8dt01597j
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资金
- University of Gottingen
- Netherlands Organisation for Scientific Research (NWO VIDI grant)
The synthesis of mono(formazanate) iron complexes is described. In the presence of tetrabutylammonium halides, salt metathesis reactions afford the ferrate(ii) complexes [Bu4N][LFeX2] (L = PhNNC(p-tol)NNPh; X = Cl, Br) in good yield, and the products are characterized in detail. The high-spin ferrate(ii) complexes show cyclic voltammograms that are consistent with reversible, ligand-based one-electron reduction. The halides in these ferrate(ii) compounds are labile, and are displaced by 4-methoxyphenyl isocyanide (4 equiv.) as evidenced by formation of the low-spin, cationic octahedral complex [LFe(CNC6H4(p-OMe))(4)][Br]. Thus, a straightforward route to mono(formazanate) iron(ii) complexes is established.
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