期刊
DALTON TRANSACTIONS
卷 47, 期 17, 页码 6075-6088出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8dt00815a
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The germanides YPtGe2 and GdPtGe2 were synthesized from REGe2 precursor compounds and platinum by arc-melting and their structures were studied on the basis of temperature-dependent single crystal X-ray diffraction data. At room temperature both germanides adopt the orthorhombic YIrGe2 type structure, space group Immm, with enhanced U-11 displacement parameters for the Ge1 atoms. Below 174 and 145 K, respectively, satellite reflections emerge in the diffraction patterns, giving rise to modulations. The low-temperature structures were refined in the superspace group Pnnn(1/2,1/2,gamma)qq0 (48.1.11.3). The structural phase transition is also evident in the magnetic susceptibility, specific heat and resistivity data. The high-and low-temperature modifications are discussed on the basis of a group-subgroup scheme.
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