期刊
DALTON TRANSACTIONS
卷 47, 期 28, 页码 9226-9230出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8dt02196a
关键词
-
资金
- French National Agency [ANR-15-CE29-0019]
- CNRS
- Ecole polytechnique
- DGA
The divalent samarium triflate salt does not react with CO2 or water, but does react with traces of O-2 or N2O to form a tetrameric bis-oxo samarium motif. The reaction with O-2 is a 4e(-) reductive cleavage where the electrons are coming from four different samarium centers. This highlights a rare synergistic effect for cleaving O-2, which has no precedent in divalent lanthanide complexes. Additionally, the addition of CO2 to the tetrameric bis-oxo intermediate leads to the formation of a tetrameric bis-carbonate samarium triflate. Thus, the concomitant reaction of CO2 with traces of O-2 leads to the same bis-carbonate tetrameric assembly.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据