期刊
DALTON TRANSACTIONS
卷 47, 期 17, 页码 5948-5951出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8dt00684a
关键词
-
资金
- National Science Centre (Poland) [UMO-2016/23/B/ST5/00177]
The first example of sodium triethylborohydride-catalyzed C(sp)-H bond silylation is reported. The reaction of aromatic and aliphatic alkynes with aromatic hydrosilanes and hydrosiloxanes proceeded in a highly selective manner to afford dehydrocoupling products. Competitive hydrosilylation of the terminal alkyne did not occur as a side-reaction. In view of the above it is remarkable that NaHBEt3 is commonly used as a reducing agent generating active transition-metal catalysts in situ in other hydrosilylation reactions.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据