期刊
DALTON TRANSACTIONS
卷 47, 期 6, 页码 1791-1795出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7dt01329a
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资金
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- Canada Foundation for Innovation (CFI)
- Grants-in-Aid for Scientific Research [16K13962, 26288023, 17H03030] Funding Source: KAKEN
A formal N-heterocyclic carbene insertion into the B-H bond of 9-BBN followed by a ring expansion reaction is reported. NHC-9BBN adducts were reacted in one or two steps to give the corresponding di-or triazaborines. Hydride abstraction of selected species with [Ph3C](+) is facile, giving rise to 6 pi-aromatic cations with Lewis acidity comparable to Lewis acids commonly employed in frustrated Lewis pairs.
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