期刊
CORROSION SCIENCE
卷 142, 期 -, 页码 119-132出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2018.07.007
关键词
Aluminium; Copper; Intermetallics; Metal coatings; Cyclic voltammetry; EIS
资金
- French Ministry of Economy and industry (BPI-France)
- Region Occitanie/Pyrenees-Mediterranee
- European Union (FEDER/ERDF)
The influence of 2024 aluminium alloy microstructure on the protective properties of trivalent chromium process (TCP) coatings was studied: samples aged at 190 degrees C were analysed by comparison to a T3 state. The surface Cu coverage after deoxidation was higher for long-aged samples because nanometer scale Cu-rich precipitates formed during ageing behaved as distinct electrochemical entities and contributed to the formation of copper deposits. The growth mechanisms and kinetics of TCP coatings were directly related to the surface Cu coverage: thicker but more defective TCP coatings formed on long-aged samples leading to the lowest anti-corrosion properties.
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