A review on corrosion protection with single-layer, multilayer, and composites of graphene

In this review, most of the works are attempted to cover about corrosion protection of metals with molecular-tight atomic thin carbon layers of all sorts of graphene derivatives from the very beginning to the latest theoretical and experimental research findings, so as engineering achievements in the field up to date. Although high and tuneable electrical conductivity of graphene is the main feature exploited in majority of the applications such as catalysis, photocatalysis, electrocatalysis, low electrical but high chemical resistivity electrodes in batteries, and ultracapacitors, corrosion protection of metals favours the opposite - good physical separation and electrical insulation. Both of the latter ones lead to durable excellent protection, which can only be ensured by special design and implementation. Thus, the milestones of major hardships both on theoretical and practical sides are delineated similarly as utmost developments in circumventing all problems with an aim to ensure timely transfer from the research phase to successful industry utilisations. Relying on numerous works, this paper gives a comprehensive overview in the subjects of preparation, modification, and use of multiple sorts of graphene in the forms of neat, combined layers, and composite coatings on numerous metals. All performance parameters are given in detail. Chronological order of the article serves the purpose to give the reader a clear picture and an important clue on viability of strategies in the aspects of environmental friendliness, attainable maximum durability, and performance of corrosion protection with graphene films, as well as further advancements in the field expected to occur in the near future.