期刊
COORDINATION CHEMISTRY REVIEWS
卷 355, 期 -, 页码 101-115出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2017.07.016
关键词
Dinuclear platinum(II) complex; Pt center dot center dot center dot Pt electronic interaction; Metal-metal-to-ligand charge transfer; Luminescence; Chromic behavior; Mixed-valent state
资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan [2406, JP15H00858, 2903, JP17H06367, JP15K17827]
- Murata Science Foundation, Japan
- Grants-in-Aid for Scientific Research [17H06367, 15K17827] Funding Source: KAKEN
Double-decker platinum complexes with N-heteroaromatic ligands have attracted increasing interest due to their outstanding luminescent properties and rich redox behavior. In this review, the design principles and recent observations on luminescent and redox-active double-decker platinum complexes are discussed. Because these properties are precisely controlled by intra- and intermolecular Pt center dot center dot center dot Pt electronic interactions, double-decker platinum complexes have been also used to obtain phenomena driven by stimulus-responsive color and luminescence change, such as vapochromism, mechanochromism, thermochromism, and electrochromism. This review also summarizes chromic materials based on double-decker platinum complexes influenced by changes in the Pt center dot center dot center dot Pt electronic interactions. (C) 2017 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据