期刊
COORDINATION CHEMISTRY REVIEWS
卷 362, 期 -, 页码 1-23出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2018.02.008
关键词
Metal-organic frameworks; Porous materials; Derivatives; Catalysis
资金
- NSFC [21725101, 21673213, 21521001, 21701093]
- National Research Fund for Fundamental Key Project [2014CB931803]
- NSF of Shandong Province [ZR201702200574]
Metal-organic frameworks (MOFs), constructed by metal ions/clusters and organic linkers, featuring crystalline porous structures, have been intensively employed as templates/precursors for the synthesis of diverse porous materials including porous carbons, metal-based compounds (such as metal oxides/carbides/phosphides) and their composites. The large surface area, high porosity and excellent tailorability of MOFs can be well inherited to their derivatives, making MOF-derived porous materials very promising for catalytic applications. Herein, we systematically summarize the versatile synthetic strategies to fabricate MOF-derived porous materials and give an overview on their recent progress on organic heterogeneous catalysis, photocatalysis and electrocatalysis. Finally, the challenges and prospects related to MOF-derived porous materials for catalysis are also discussed. (C) 2018 Elsevier B.V. All rights reserved.
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