期刊
CONSTRUCTION AND BUILDING MATERIALS
卷 165, 期 -, 页码 866-876出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.conbuildmat.2018.01.080
关键词
Polyesters; Langmuir adsorption; Simulated concrete pore; Cathodic inhibition; Barrier
资金
- KU Research Professor Program of Konkuk University
As a motto of framing the strategies to minimise the deterioration in steel reinforced concrete structures as well as the fact that the work carried out with polymers are rare and scanty, polyesters namely Poly (Glycerol azealate) (PGAZ) and 4-(1-(4-methoxy phenyl) cyclo hexyl)phenyl 9-oxodecanoate (MPOD) were synthesised and evaluated for rebar corrosion in simulated concrete pore solution (SCP) for the first time at selected concentrations of 10, 100, 1000 ppm levels with an aid of electrochemical impedance and potentiodynamic polarisation techniques. Nyquist plots favoured increased R-ct values suggesting the formation of barrier. Tafel plots represented cathodic inhibition. The experimental datas were best fitted with Langmuir adsorption isotherm facilitating monolayer adsorption. Both the methods employed were in good agreement with each other favouring maximum inhibition efficiency of 71.81% for MPOD and minimum of 57.64% for PGAZ primarily due the difference in aromatic sites as revealed in mechanism. (C) 2018 Elsevier Ltd. All rights reserved.
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