期刊
COMPOSITES PART B-ENGINEERING
卷 133, 期 -, 页码 203-209出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.compositesb.2017.09.040
关键词
Particle-reinforcement; Polymer-matrix composites (PMCs); Mechanical properties; Thermal analysis
资金
- K. C.Wong Magna Fund in Ningbo University
- Foundation of Ningbo University [XYL17025]
- Research Funds of NBU [ZX2016000752]
- Applied Research Project on Public Welfare Technology of Zhejiang Province [2016C33103]
- Natural Science Foundation of Zhejiang Province [LY16E030003]
To improve the mechanical and thermal properties of poly (lactic acid) (PLA) composites, bamboo cellulose nanowhiskers (BCNW) were extracted and introduced into PLA composites as fillers. PLA/BCNW biofilms were fabricated by solution casting with different BCNW contents (0, 0.5, 1.0, 1.5, 2.0, 2.5, 3.0, 3.5, and 4.0 wt%). The characteristics of the biofilms were investigated by scanning electron microscopy (SEM), mechanical measurements, synchrotron radiation wide-angle X-ray scattering (WAXS) and differential scanning calorimetry (DSC). The results showed that the maximum tensile modulus and elongation at break of 427.72 +/- 19.32 MPa and 22.27 +/- 3.50% were reached at 2.5 wt% and 1.0 wt% loadings, respectively. Both homogeneity and stereocomplexed crystallites were observed, and heterogeneous nucleation effect was confirmed. With the addition of BCNW, the crystallite size of PLA/BCNW composites increased remarkably, and the largest crystallinity was 30.7 +/- 0.9% with 2.5 wt% BCNW. These results provided data support for enlarging the application of PLA. (C) 2017 Elsevier Ltd. All rights reserved.
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