期刊
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
卷 3, 期 4, 页码 2647-2661出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.jece.2015.09.028
关键词
Biosorption; Dried sunflower seed hull; Textile dye wastewater; Kinetics; Thermodynamics; Single stage absorber
Alkali treated dried sunflower seed hull (DSSH) was used as adsorbent for the decolorization of wastewater effluent from the textile industry. Batch adsorption studies were performed as a function of contact time, initial solution pH, initial dye concentration, adsorbent dosage and temperature. Kinetic analysis revealed that adsorption experimental data was best fitted by pseudo-second order model at all textile dye concentrations tested. Based on the pseudo-second order rate constants obtained using Arrhenius and Eyring equations, the activation parameters for the formation of activated complex between Textile dye molecules and dried sunflower seed hull were determined: namely the activation energy (8.79 kJ/mol), the change of entropy (-39.57 kJ/mol/K), enthalpy (8.79 kJ/mol), and Gibbs free energy (range 6.27-8.11 kJ/mol). The equilibrium adsorption data was found to follow the Langmuir isotherm model and maximum monolayer capacity was found to be 169.5 mg/g at 25 degrees C. The Langmuir isotherm model was applied to the design of a single-stage adsorber. From the thermodynamics analysis the magnitude of enthalpy change (Delta H) was found to be 8.79 kJ/mol; indicating that physical forces were involved in biosorption of dye onto DSSH. (C) 2015 Elsevier Ltd. All rights reserved.
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