期刊
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
卷 553, 期 -, 页码 187-194出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.colsurfa.2018.05.029
关键词
Lignin; Microwave-assisted; Carboxymethylation; Lead; Adsorption
资金
- Natural Science Foundation of Guangdong Province [2017A030308012]
- Science and Technology Program of Guangdong Province [2017B090903003]
- Fundamental Research Funds for the Central Universities [2015ZZ120]
An efficient lignin adsorbent for Pb2+ in water was synthesized by crosslinking microwave-assisted carboxymethyl lignin (C-MCML) and the saturated adsorption capacity for Pb2+ was 302.3 mg/g. Microwave irradiation showed a greater assisted ability in the carboxyrnethylation than that of traditional heating, and the carboxyl content of microwave-assisted carboxymethyl lignin could be raised to 3.61 mmol/g. The adsorption behavior of C-MCML also was studied by varying different parameters like pH, initial concentration of metal ions and shaking time. The adsorption isotherm was fitted well by Langmuir model, and the fitting saturated adsorption capacity was 323.6 mg/g. Meanwhile, the results of FTIR and XPS shown that main Pb2+ adsorption mechanimis was ion exchange by carboxyl. The adsorption capacity of C-MCML was still maintained at 90% after recycled for 10 times.
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