期刊
RSC ADVANCES
卷 5, 期 122, 页码 100452-100456出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra21610a
关键词
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资金
- National Natural Science Foundation of China [21202138, 21302051]
- Xiangtan University Academic Leader Program [11QDZ20]
- New Teachers' Fund for Doctor Stations, Ministry of Education [20124301120007]
- Hunan Provincial Natural Science Foundation [13JJ4047]
- Hunan Provincial Excellent Young Scientist Foundation [13B114]
A rhodium-catalyzed oxidative decarbonylative Heck-type coupling of aromatic aldehydes with terminal alkenes to afford 1,2-disubstituted alkenes with good regio-and E-selectivity is developed. This reaction employs readily available aromatic aldehydes as the aryl electrophile counterpart and relies on selected acyl chloride as the crucial additive to activate the rhodium catalyst precursor.
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