期刊
CHINESE JOURNAL OF CHEMISTRY
卷 36, 期 8, 页码 743-748出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.201800169
关键词
metal migration; naphthalene; palladium; annulation; alkyne
资金
- National Natural Science Foundation of China [21472212, 21572253, 21772216]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB 20020100]
- Key Research Program of Frontier Science [QYZDY-SSW-SLH026]
The palladium catalyzed annulation of 1-bromo-2-vinylbenzene derivatives with internal alkynes was realized for the efficient synthesis of substituted naphthalenes. A controllable aryl to vinylic 1,4-palladium migration process is the key for success.
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