期刊
CHEMSUSCHEM
卷 11, 期 13, 页码 2255-2261出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201800786
关键词
batteries; hierarchical microspheres; iron phosphate; lithium; reduced graphene oxide
资金
- National Natural Science Foundation of China [21261130584, 91022030, 21771081]
- Chang Bai Mountain Scholars Program [440020031182]
- Provincial major project [21390394]
- National Materials Genome Project [2016YFB0700600]
- National Project for EV Batteries [20121110]
- Shenzhen Science and Technology Research Grant [ZDSY20130331145131323, JCYJ20140903101633318, JCYJ20140903101617271]
- Guangdong Innovation Team Project [2013N080]
- China Postdoctoral Science Foundation [2017M620497, 2017M620520]
LiFePO4@C/reduced graphene oxide (rGO) hierarchical microspheres with superior electrochemical activity and a high tap density were first synthesized by using a Fe3+-based single inorganic precursor (LiFePO4OH@RF/GO; RF=resorcinol-formaldehyde, GO=graphene oxide) obtained from a template-free self-assembly synthesis followed by direct calcination. The synthetic process requires no physical mixing step. The phase transformation pathway from tavorite LiFePO4OH to olivine LiFePO4 upon calcination was determined by means of the insitu high-temperature XRD technique. Benefitting from the unique structure of the material, these microspheres can be densely packed together, giving a high tap density of 1.3gcm(-3), and simultaneously, defectless LiFePO4 primary nanocrystals modified with a highly conductive surface carbon layer and ultrathin rGO provide good electronic and ionic kinetics for fast electron/Li+ ion transport.
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