期刊
CHEMPHYSCHEM
卷 19, 期 16, 页码 2025-2036出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cphc.201800138
关键词
host-guest systems; ion-recognition; lead(II) ion detection; responsive microgels; smart materials
资金
- National Natural Science Foundation of China [91434202, 21776182]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT15R48]
- State Key Laboratory of Polymer Materials Engineering [sklpme2014-1-01]
A simple device, which is equipped with a non-woven fabric filter medium immobilized with ion-recognizable smart hollow microgels, is developed for facile detection of trace lead(II) ions (Pb2+). The ion-recognizable smart microgels are made of poly(N-isopropylacrylamide-co-benzo-18-crown-6-acrylamide) (PNB), in which the 18-crown-6 groups act as the sensors of Pb2+ and the N-isopropylacrylamide groups act as the actuators. The PNB hollow microgels can isothermally change from a shrunk state to a swollen state in response to recognizing Pb2+ in the aqueous environment due to the electrostatic repulsion among the charged 18-crown-6/Pb2+ complex groups and the enhancement of hydrophilicity of the microgels. Due to the hollow structures, the PNB microgels show remarkable isothermal swelling ratio. Thus, the flux of solution pass through the non-woven fabric filter medium decreases significantly because of the remarkable reduction in the space for liquid flowing upon recognizing Pb2+. The Pb2+ concentration can be detected quantitatively by simply and easily measuring the change of solution flux using the proposed device, which is operated without external power supply or spectroscopic measurements. The strategy proposed in this study provides a promising method for facile detection of trace Pb2+ in aqueous environments.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据