期刊
CHEMISTRY-AN ASIAN JOURNAL
卷 13, 期 17, 页码 2257-2276出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201800583
关键词
carbenes; homogeneous catalysis; metal-organic frameworks; nitrogen heterocycles; palladium
资金
- NSFC [21722105, 21531007, 21771146]
- National Youth Top-Notch Talent Support Program of China
- Scientific Research Foundation for Returned Overseas Scholars of Shaanxi Province [2017001]
- Shaanxi Key Laboratory of Physical-Inorganic Chemistry [17JS133]
- Top-Rated Discipline Construction Scheme of Shaanxi Higher Education
- FM & EM International Joint Laboratory of Northwest University
N-Heterocyclic carbenes (NHCs) have been widely employed in the construction of various metal complexes and applied in the field of catalysis. In this review, a series of palladium complexes comprising chelating bis(NHC) donors (Pd-bis(NHC) complexes) are outlined according to their application in homogeneous catalysis. Examples of metal-organic frameworks containing Pd-bis(NHC) moieties are briefly discussed, in terms of their use in heterogeneous catalysis. The catalytic applications of Pd-bis(NHC) complexes (or moieties in heterogeneous catalysts) are mainly focused on the Mizoroki-Heck, Suzuki-Miyaura, and Sonogashira coupling reactions. Another 14 types of reactions are also summarized beyond these three types of reactions.
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