期刊
CHEMISTRY-AN ASIAN JOURNAL
卷 13, 期 17, 页码 2414-2417出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201800536
关键词
asymmetric synthesis; organoboron compounds; palladium; stereospecific reaction; synthetic methods
资金
- JSPS KAKENHI [JP23655082, JP26288048, JP15H05811]
- Nikko Memorial Agency
Suzuki-Miyaura coupling of nonbenzylic -(acylamino)alkylboron compounds with aryl halides is established. A Pd/PCy2Ph catalyst promotes the reaction efficiently at 145 degrees C. The reaction of enantioenriched -(acylamino)alkylboron compounds affords chiral 1-arylalkylamides in high enantiospecificity and inversion of configuration.
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