期刊
CHEMISTRY-AN ASIAN JOURNAL
卷 13, 期 6, 页码 631-635出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201701647
关键词
carbon dioxide separation; membranes; metal-organic frameworks; mixed-matrix membrane; open metal sites
资金
- Korea Institute of Energy Research (KIER) [B7-2461-02, B8-2431]
- Center for Advanced Meta-Materials (CAMM) - Ministry of Science and ICT (MSIT) [2014063701, 2014063700]
- MSIT
- POSTECH
Defect-free mixed-matrix membranes (MMMs) were prepared by incorporating hydrophilic metal-organic polyhedra (MOPs) into cross-linked polyethylene oxide (XLPEO) for efficient CO2 separation. Hydrophilic MOPs with triethylene glycol pendant groups, which were assembled by 5-tri(ethylene glycol) monomethyl ether isophthalic acid and Cu-II ions, were uniformly dispersed in XLPEO without particle agglomeration. Compared to conventional neat XLPEO, the homogenous dispersion of EG(3)-MOPs in XLPEO enhanced CO2 permeability of MMMs. Upon increasing the amount of EG(3)-MOPs, the membrane performance such as CO2/N-2 selectivity was steadily improved because of unsaturated Cu-II sites at paddle-wheel units, which was confirmed by Cu K-edge XANES and TPD analysis. Therefore, such defect-free MMMs with unsaturated metal sites would contribute to enhance CO2 separation performance.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据