期刊
CHEMISTRY-AN ASIAN JOURNAL
卷 13, 期 17, 页码 2410-2413出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201800529
关键词
aldehydes; carboxylic acids; bioisosteres; dehomologation; photoredox catalysis
资金
- ERATO program from JST [JPMJER1302]
- JSPS KAKENHI [JP17H04868]
- JSPS Summer Programme
- Uehara Memorial Foundation
- World Premier International Research Center Initiative (WPI), Japan
A photoredox-catalyzed decarboxylative oxidation of arylacetic acids, which are privileged scaffolds in pharmaceuticals, is reported herein. The established method is operationally simple and a variety of substrates are applicable, providing rapid access to dehomologated bioisosteres of common pharmaceuticals.
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