期刊
CHEMISTRY-AN ASIAN JOURNAL
卷 13, 期 17, 页码 2388-2392出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201800462
关键词
C-H functionalization; diazo; metal-carbene; quinoline N-oxide; Rhodium
资金
- CSIR, India [02(0323)/17/EMR-II]
- DST, India [SR/FST/CSII-026/2013]
An efficient Rh-III-catalyzed redox-neutral method for the direct C8-arylation of quinoline N-oxides using diazonaphthalen-2(1H)-one as coupling partner has been demonstrated. The developed method is simple, scalable and straightforward with a wide range of substrate scope. The applicative potential was extended with a late-stage functionalization and straightforward synthesis of 8-azaBINOL derivative. A plausible reaction pathway was proposed after carrying out preliminary control studies.
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