期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 24, 期 40, 页码 10064-10068出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201802352
关键词
C-H functionalization; heteroarenes; methylation; methylthiomethylation; photoredox catalysis
资金
- Alexander von Humboldt Foundation
- Deutsche Forschungsgemeinschaft
- NRW Graduate School of Chemistry
Herein, we report a novel strategy for the activation of DMSO to act as a versatile alkylating agent in heteroarene C-H functionalization. This direct, simple, and mild switch between methylation/trideuteromethylation and methylthiomethylation of heteroarenes was achieved under reagent-controlled photoredox catalysis conditions. The proposed mechanism is supported by both experimental and computational studies.
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