期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 24, 期 38, 页码 9692-9697出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201801471
关键词
carbenes; cyclic (alkyl)(amino)carbenes; digallanes; gallium; halogen exchange
资金
- Deutsche Forschungsgemeinschaft
A range of double carbene adducts of digallanes(4) are prepared from an existing double digallane adduct, and their halides are subsequently exchanged, establishing the feasibility of both base and halide-exchange reactions from digallane adducts. Furthermore, a range of digallium species are treated with transition-metal Lewis bases, leading alternatively to oxidative addition products, species with monocoordinate Ga+ ligands, and an unusual ditopic metal-only Lewis pair (MOLP). These results underline the manifold and unpredictable chemistry of halogallane species with Lewis bases.
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