期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 24, 期 52, 页码 13719-13727出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201801574
关键词
alloying reaction; antimony; batteries; bismuth; sodium
资金
- National Natural Science Foundation of China [51672182, 51772197]
- Thousand Young Talents Plan
- Jiangsu Natural Science Foundation [BK20151219, BK20140009]
- Key University Science Research Project of Jiangsu Province [17KJA430013]
- 333 High-Level Talents Project in Jiangsu Province
- Six Talent Peaks Project in Jiangsu Province
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
- RFBR [18-13-00217]
Sodium-ion batteries (SIBs) that efficiently store electricity into chemical energy have been extensively pursued because of their great potential for low-cost and large-scale stationary application such as smart grid and renewable energy. Successful deployment of SIBs requires efficient anode materials that could store Na+ ions via a reversible way at reasonable rates. Materials based on antimony and bismuth are capable of storing a high-concentration of Na+ ions via a reversible alloying reaction at suitable redox potentials, and thus have drawn substantial attention. However, these electrode materials are facing significant technical challenges, such as poor conductivity, multiple phase transformation, and severe volume swelling and shrinking, which make efficient materials design a necessity. In this review, we will give a latest overview of research progress in the design and application of electrode materials based on antimony and bismuth, and offer some value insights into their future development in sodium storage.
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