期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 24, 期 7, 页码 1726-1731出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201705634
关键词
C-H activation; exciplex; green chemistry; hydroacylation; photo-organocatalysis
资金
- Latsis Foundation
- National Scholarship Foundation (IKY)
- COST Action C-H Activation in Organic Synthesis (CHAOS) [CA15106]
Selective C-H activation is an area of growing importance. Metal-free C-H activation of branched aldehydes mediating the hydroacylation of electron-deficient alkenes is an attractive transformation, but is limited by selectivity issues, especially in the case of alpha,alpha-disubstituted aldehydes. Herein, we report a green, cheap, versatile, and easily reproducible selective hydroacylation of alkenes utilizing phenylglyoxylic acid as the photocatalyst and common household bulbs for irradiation, leading to products in excellent yields and selectivities. The reaction mechanism was also studied to account for the high selectivity.
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