期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 24, 期 33, 页码 8315-8319出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201801804
关键词
1,6-addition; asymmetric catalysis; boron; copper; enantioselectivity
资金
- European Research Council [258580]
- Engineering and Physical Sciences Research Council [EP/I004769/1, EP/I004769/2, EP/H031588/1]
- Pfizer
- GlaxoSmithKline
- University of Nottingham
- EPSRC [EP/I004769/2, EP/I004769/1] Funding Source: UKRI
The enantioselective Cu-catalyzed 1,6-boration of (E,E)-alpha,beta,gamma,delta-unsaturated ketones is described, which gives homoallylic boronates with high enantiomeric purity and unexpectedly high Z-selectivity. By changing the solvent, the outcome can be altered to give E-allylic boronates.
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