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Iodonium Salts as Benzyne Precursors

期刊

CHEMISTRY-A EUROPEAN JOURNAL
卷 24, 期 57, 页码 15156-15166

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201802111

关键词

arynes; benzyne precursors; cycloaddition; hypervalent iodine; iodonium

资金

  1. Tomsk Polytechnic University Competitiveness Enhancement Program [VIU-195/2018]
  2. National Science Foundation [CHE-1759798]
  3. JSPS [16KK0199]
  4. Grants-in-Aid for Scientific Research [16KK0199] Funding Source: KAKEN

向作者/读者索取更多资源

Reactions involving benzyne and aryne intermediates have found widespread application in organic synthesis. Various benzyne precursors and benzyne generating procedures are known. Recently, methods of benzyne generation from diaryliodonium salts and related hypervalent iodine compounds have received considerable attention. These methods are characterized by mild reaction conditions and applicability in a broad range of chemical transformations. The present minireview is focused on the preparation and reactivity of hypervalent iodine based benzyne precursors. Furthermore, recent developments in their synthetic application are discussed.

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