期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 24, 期 57, 页码 15156-15166出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201802111
关键词
arynes; benzyne precursors; cycloaddition; hypervalent iodine; iodonium
资金
- Tomsk Polytechnic University Competitiveness Enhancement Program [VIU-195/2018]
- National Science Foundation [CHE-1759798]
- JSPS [16KK0199]
- Grants-in-Aid for Scientific Research [16KK0199] Funding Source: KAKEN
Reactions involving benzyne and aryne intermediates have found widespread application in organic synthesis. Various benzyne precursors and benzyne generating procedures are known. Recently, methods of benzyne generation from diaryliodonium salts and related hypervalent iodine compounds have received considerable attention. These methods are characterized by mild reaction conditions and applicability in a broad range of chemical transformations. The present minireview is focused on the preparation and reactivity of hypervalent iodine based benzyne precursors. Furthermore, recent developments in their synthetic application are discussed.
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