期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 24, 期 17, 页码 4264-4267出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201800312
关键词
halogen bonds; host-guest systems; pillararenes; polypseudorotaxanes; self-assembly
资金
- National Natural Science Foundation of China [21434005, 91527310]
Linear side-chain polypseudorotaxane with supramolecular polymer backbone was assembled by neutral halogen bonds (XB) and pillar[5]arene-based host-guest interactions in solution and in the solid state. The formation of the halogen-bonded supramolecular polymer backbone and side-chain polypseudorotaxane in solution was characterized by (HNMR)-H-1 spectroscopy, diffusion ordered NMR spectroscopy and scanning electron microscopy experiments. Furthermore, the solid-state structures of these two highly organized supramolecular architectures were provided by single-crystal X-ray analysis.
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