期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 24, 期 37, 页码 9269-9273出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201801886
关键词
ketyl radical; proton-coupled electron transfer; photoredox catalysis; radical reactions; alpha-amino radicals
资金
- National Natural Science Foundation of China [21732002, 21562023, 21672117]
- Tianjin Natural Science Foundation [16JCZDJC32400]
A photoredox-catalyzed umpolung strategy for coupling reactions between aldehydes, ketones, imines, and N-arylamines is reported. These reactions proceed by a BrOnsted acid-activated proton-coupled electron transfer pathway, and the protocol was used to synthesize a broad scope of 1,2-amino alcohols and vicinal diamines, both of which are common motifs in biologically active natural products, pharmaceutically active molecules, and ligands.
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