期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 24, 期 21, 页码 5479-5483出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201706101
关键词
colloid; Hofmeister series; macromolecule; polyoxometalate; Schulze-Hardy rule
资金
- NSF [CHE1607138]
- Materials Science of Actinides Center, an Energy Frontier Research Center - U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-SC0001089]
- University of Akron
The Schulze-Hardy rule is a well-established observation in colloid science (can be derived from the DLVO theory) that demonstrates the relationship between the critical coagulation concentration (CCC) of colloids and the valence of extra counterionic electrolytes (z), with a simple mathematical relationship of CCC approximate to z(-6). Here the Schulze-Hardy Rule is expanded to much smaller, nano-scaled soluble macroions in aqueous solution, by examining the stability of the macroions in the presence of additional electrolytes. The CCC values of the macroions follow the general trend of CCC approximate to z(-n) but the n value is significantly dependent on the surface charge density of the macroions, ranging from n = 2 at very low surface charge density to n = 6 at a high surface charge density. In addition, different cations with the same valence showed clear different impacts on the CCC values, with an interesting trend being connected to the Hofmeister series originally discovered in protein solutions.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据