期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 24, 期 41, 页码 10403-10408出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201800728
关键词
biomass; isomerization; macrocyclization; metathesis; musk
资金
- Polish-Singapore Grant Green and Sustainable Catalysts for Chemical, Agrochemical and Pharmaceutical Industry 2012-2015 NCBR [3/3/POL-SIN/2012]
- US NSF [CHE-14164781]
We report successful utilization of sequential alkene isomerization and ring-closing metathesis of dec-9-enoic acid based dienes in synthesis of macrocyclic lactones that possess a strong scent of musk. This catalytic sequence was essential to trim the chain length of starting dienes to yield macrocycles of the right size. Dec-9-enoic acid is conveniently obtainable from oleic esters by Ru-catalysed ethenolysis.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据