期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 24, 期 28, 页码 7128-7132出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201801414
关键词
1,1'-binaphthyls; aggregation-induced phosphorescence; chiral Pt-II Salen complex; circularly polarized luminescence; near-infrared emission
资金
- National Natural Science Foundation of China [21372169]
A series of chiral and helical Pt-II-Salen complexes with 1,1'-binaphthyl linkers were synthesized and characterized. Owing to the restriction of intramolecular motions of central 1,1'-binaphthyls, the complexes exhibit unusual near-infrared aggregation-induced phosphorescence (AIP). The (R)/(S) enantiopure complexes were characterized by X-ray diffraction, circular dichroism spectra, time-dependent density functional theory calculations, and circularly polarized luminescence (CPL). The present work explores the use of tetradentate ligands that can be easily prepared from commercially available enantiopure compounds, and the subsequent preparation of stable CPL-active square planar Pt-II complexes with AIP effect that may have interest in many applications.
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