期刊
CHEMICAL SOCIETY REVIEWS
卷 47, 期 7, 页码 2322-2356出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cs00543a
关键词
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资金
- National Key Research and Development Program of China [2017YFA0207002]
- National Natural Science Foundation of China [21577032, 21477133]
- Fundamental Research Funds for the Central Universities [JB2015001]
Highly efficient removal of metal ion pollutants, such as toxic and nuclear waste-related metal ions, remains a serious task from the biological and environmental standpoint because of their harmful effects on human health and the environment. Recently, highly porous metal-organic frameworks (MOFs), with excellent chemical stability and abundant functional groups, have represented a new addition to the area of capturing various types of hazardous metal ion pollutants. This review focuses on recent progress in reported MOFs and MOF-based composites as superior adsorbents for the efficient removal of toxic and nuclear waste-related metal ions. Aspects related to the interaction mechanisms between metal ions and MOF-based materials are systematically summarized, including macroscopic batch experiments, microscopic spectroscopy analysis, and theoretical calculations. The adsorption properties of various MOF-based materials are assessed and compared with those of other widely used adsorbents. Finally, we propose our personal insights into future research opportunities and challenges in the hope of stimulating more researchers to engage in this new field of MOF-based materials for environmental pollution management.
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