期刊
CHEMICAL SOCIETY REVIEWS
卷 47, 期 16, 页码 6013-6045出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cs00299a
关键词
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资金
- National Creative Research Initiative (CRI) Center for Multi-Dimensional Directed Nanoscale Assembly [2015R1A3A2033061]
- Nanomaterial Technology Development Program through the National Research Foundation of Korea (NRF) - Ministry of Science, ICT and Future Planning [NRF-2016M3A7B4905609]
- Basic Science Research Program of the National Research Foundation of Korea [2017R1A2B4010771]
Graphene, despite being the best known strong and electrical/thermal conductive material, has found limited success in practical applications, mostly due to difficulties in the formation of desired large-scale highly organized structures. Our discovery of a liquid crystalline phase formation in graphene oxide dispersion has enabled a broad spectrum of highly aligned graphene-based structures, including films, fibers, membranes, and mesoscale structures. In this review, the current understanding of the structureproperty relationship of graphene oxide liquid crystals (GOLCs) is overviewed. Various synthetic methods and parameters that can be optimized for GOLC phase formation are highlighted. Along with the results from different characterization methods for the identification of the GOLC phases, the typical characteristics of different types of GOLC phases introduced so far, including nematic, lamellar and chiral phases, are carefully discussed. Finally, various interesting applications of GOLCs are outlined together with the future prospects for their further developments.
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