期刊
CHEMICAL ENGINEERING JOURNAL
卷 351, 期 -, 页码 939-951出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2018.06.151
关键词
Waterborne coating; Anticorrosion; Graphene; Poly(urethane-acrylate); Tinplate
资金
- National Natural Science Foundation of China [51373091]
- scientific research foundation (SRF) for returned overseas Chinese scholars (ROCS)
- State education ministry (SEM) [[2012] 1707]
- Key Research and Development Project of Shannxi Province [2017GY-154, 2018KW-007]
- Key Laboratory Project of Education Bureau of Shaanxi Province [16JS011]
Homogeneous dispersion of graphene (GR) in waterborne polymer matrix still remains a challenge. In this work, a novel strategy to prepare waterborne graphene/polymer nanocomposite of high uniformity and stability is developed via in situ incorporation of cationic graphene (CGR) in anionic poly(urethane-acrylate) (WPUA) prepolymer. Compared to WPUA and GR-WPUA, the water resistance, tensile strength and anticorrosive properties of CGR-WPUA are significantly increased. With respect to WPUA and GR-WPUA coatings with 0.5% GR addition, the impedance modulus at lower frequency decreased by one order of magnitude and the coating resistance decreased by two orders of magnitude after 25 days of immersion. While the impedance modulus and coating resistance of 0.5% CGR-WPUA are of the same order before and after immersion. The as-prepared CGR-WPUA coating was endowed with superior long-term anticorrosive properties. It is also found that the corrosion protection efficiency of CGR-WPUA increased by 78.2% in comparison to WPUA and increased by 32.0% compared with GR-WPUA. This work demonstrates the critical role of graphene-polymer interaction for anticorrosion applications of waterborne graphene/polymer nanocomposite.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据