期刊
CHEMICAL ENGINEERING JOURNAL
卷 332, 期 -, 页码 253-259出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2017.09.084
关键词
Chestnut shell-like Li4Ti5O12 hollow sphere; Electrode material; N-doped graphene; Asymmetric supercapacitor
资金
- National Natural Science Foundation of China [21475115, 21671170]
- Program for University Innovative Research Team of Henan [15IRTSTHN001]
- Henan Provincial Science and technology innovation team [C20150026]
- XYNU
- Henan Science and Technology Cooperation Project [172106000014]
As promising electrode materials in supercapacitor, metal oxides have attracted significant attention recently. At present, it is highly desirable but remains challenging to prepare three-dimensional (3D) metal oxides hollow materials for further improving the performance of supercapacitors. Herein, 3D chestnut shell-like Li4Ti5O12 hollow sphere is successfully fabricated by using an effective hydrothermal strategy. Owing to the unique structural feature and the desirable chemical composition, Li4Ti5O12 hollow sphere displays a remarkable capacitance of 653.22 F/g at 1 A/g and keeps 88.56% over 4000 cycle. Furthermore, one aqueous asymmetric supercapacitor (ASC) is constructed based on Li4Ti5O12 and N-doped graphene oxide (NGO) which is synthesized by a facile burning method. The Li4Ti5O12//NGO ASC shows an energy density of 26.15 Wh/kg at power density of 799.83 W/kg, and yet keeps 14.45 Wh/kg even at 8.01 kW/kg. This strategy may offer a versatile idea of tailoring new type of 3D metal oxides hollow materials and opens the possibility for using in high energy storage device.
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