期刊
CHEMICAL ENGINEERING JOURNAL
卷 347, 期 -, 页码 291-300出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2018.04.113
关键词
Cobalt oxide (Co3O4); 3D CoWO4/Co3O4 nanowire arrays; Electrode; Microwave hydrothermal; Supercapacitors
资金
- National Nature Science Foundation [51672220]
- 111 Program of MOE [B08040]
- National Defense Science Foundation [32102060303]
- Xi'an Science and Technology Foundation [2017086CGRC049-XBGY005, XYCX2017-08]
- Shaanxi Provincial Science Foundation [2017KW-018]
- NPU Gaofeng Project of China [17GH020824]
A 3D hierarchical CoWO4/Co3O4 structure, with the synergetic effect of diverse materials, large specific surface area and fast transmission of electrons and ions is synthesized by a facile and efficient microwave hydrothermal method. We found that CoWO4 and 3D CoWO4/Co3O4 exhibit four pairs of redox peaks, which were discussed systematically. The hybrid electrode shows excellent specific capacitance of 1728 F g(-1) at current density of 2.7 mA cm(-2) (1 A g(-1)) with superior rate capability and satisfactory cycling stability (85.9% capacitance preserved after 5000 cycles). The asymmetric supercapacitors assembled with CoWO4/Co3O4 and activated carbon exhibit high energy density (57.8 Wh kg(-1)) and power density (6000Wkg(-1) at 40.64 Wh kg(-1)), with remarkable cycle life. The above results indicate that the ordered CoWO4/Co3O4 nanowire arrays synthesized by this approach would be a promising candidate for practical application of high-performance supercapacitors.
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