期刊
CHEMICAL ENGINEERING JOURNAL
卷 344, 期 -, 页码 12-20出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2018.03.050
关键词
Electrochemical activation of PDS; Carbon anodes; Nonradcial oxidation; Radical oxidation
资金
- National Natural Science Foundation of China [51578203]
- National Science and Technology Major Projects for Water Pollution Control and Treatment [2017ZX07201003]
- National Key Research and Development Program [2016YFC0401107]
- State Key Laboratory of Urban Water Resource and Environment (HIT) [2016DX13]
In this study, electrochemical activation of peroxydisulfate (PDS) using carbon anodes including multi-walled carbon nannotube (MWCNT), graphite (GR), black carbon (BC) and granular activated carbon (GAC) for degradation of antibiotic sulfamethoxazole (SMX) was investigated for the first time. The degradation of SMX by electrochemical activation of PDS using carbon anodes showed dual kinetics: an induction stage followed by a quick decay stage. In the latter stage, the degradation rate of SMX by electrochemical activation of PDS using MWCNT, GR, BC and GAC anodes increased about 15-35 times of that by electrolysis alone and 30-130 times of that by carbon/PDS (without applying current). The results of degradation of radical probes (atrazine (ATZ) and nitrobenzene (NB)) and radical scavenging effect manifest that nonradical oxidation, hydroxyl radical (HO%) and sulfate radical (SO4 center dot-) jointly contributed to the degradation of SMX in electrochemical activation of PDS. The formation of transition state structure of PDS (activated PDS, PDS*) between PDS molecule and carbon anodes by applying current was proposed to be responsible for nonradical oxidation, and its further decomposition resulted in the generation of HO% and SO4 center dot-. Increasing PDS concentration (0.1-5 mM) or current density (10-200 A m(-2)) considerably promoted the degradation of SMX. Additionally, electrochemical activation of PDS using carbon anodes exhibited good resistance to water matrices.
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