期刊
CHEMICAL COMMUNICATIONS
卷 54, 期 5, 页码 511-514出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc08489g
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资金
- JSPS KAKENHI [JP26106003]
- WPI
- Grants-in-Aid for Scientific Research [24619011] Funding Source: KAKEN
We report the syntheses of ribonucleoside 5'-monophosphates activated with imidazole, using a mechanism which relies on the in situ generation of cyanogen chloride from the reaction of cyanide anion with hypochlorous acid. Cyanogen chloride reacts rapidly with imidazole to form diimidazole imine as the major product, a species which affords the activation of ribonucleoside 5'-monophosphates to their 5'-phosphorimidazolides.
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