期刊
CHEMICAL COMMUNICATIONS
卷 54, 期 53, 页码 7310-7313出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc03793k
关键词
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资金
- Icelandic Research Fund [141218051, 162880051]
- University of Iceland Research Fund
- Max Planck Society
A new 1.2 angstrom crystal structure of vanadium nitrogenase, isolated under turnover conditions, recently revealed a light atom ligand (OH or NH) replacing the bridging S2B sulfide of the FeV cofactor. QM/MM calculations on the new structure now reveal the light-atom ligand to be a bridging hydroxo group, probably derived from water binding to the cofactor.
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