期刊
CHEMICAL COMMUNICATIONS
卷 54, 期 6, 页码 603-606出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc08178b
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资金
- National Natural Science Foundation of China [21763001, 21463001]
- Key Scientific Research Projects of the Higher Education Institutions of Ningxia Hui Autonomous Region [NCX2017143]
- Key Laboratory of Electrochemical Energy Conversion Technology and Application
- Key Scientific Research Projects at North Minzu University [2017KJ20]
Thiomolybdate [Mo3S13](2-) nanoclusters, as a molecular mimic of MoS2 edge sites, showed high efficiency in catalyzing photochemical H-2 evolution from a molecular system of Ru(bpy)(3)Cl-2-ascorbic acid (H(2)A) under visible light irradiation (>= 420 nm), providing a turnover number of 1570 and an initial turnover frequency of 335 h(-1) for H-2 evolution based on the [Mo3S13](2-) catalyst.
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