期刊
CHEMICAL COMMUNICATIONS
卷 54, 期 50, 页码 6911-6914出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc02570c
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资金
- National Research Foundation of Korea (NRF) - Korea government [NRF-2016R1A2B4015351, NRF-2016R1A4A1011451]
- GRRC program of Gyeonggi province [GRRCKyungHee2018-A01]
Herein, we demonstrate a new catalytic cycloaddition of quinolinium zwitterions involving a gold-bound allylic cation intermediate. This ligand-free higher-order cycloaddition efficiently affords a variety of fused 1,4-diazepine derivatives in a stereospecific manner at room temperature.
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