期刊
CHEMICAL COMMUNICATIONS
卷 54, 期 58, 页码 8088-8091出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc03496f
关键词
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资金
- Department of Energy, Basic Energy Sciences, and Division of Materials Sciences and Engineering [DE-FG02-08ER-46491]
- Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy [DE-AC02-05CH11231]
- National Natural Science Foundation of China [21371103]
- 111 Project [B12015]
- China Scholarship Council (CSC) [201606200043]
We report herein a new two-dimensional zirconium-based luminescent coordination polymer Zr-6(sdba)(4)(mu(3)-O)(4)(mu(3)-OH)(4)(HCOO)(2)-(OH)(2)(H2O)(2) (1) [sdba = 4,4'-sulfonyldibenzoate] exhibiting selective fluorescence responses towards a variety of volatile organic compounds upon exposure in the vapor phase. Having a unique two-dimensional signal response towards aromatic molecules, including but not limited to nitroaromatic explosives, it is capable of identifying a diverse set of analytes. In addition, compound 1 shows its remarkably high sensitivity toward acetone vapors.
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