期刊
CHEMICAL COMMUNICATIONS
卷 54, 期 14, 页码 1770-1773出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc09432a
关键词
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资金
- National Key Research and Development Program of China [2016YFA0602900]
- National Natural Science Foundation of China [21420102003]
- Fundamental Research Funds for the Central Universities [2015ZY001]
A palladium(II)-catalyzed hydroboration of aryl alkenes with stable and easy-to-handle (pinacolato) diboron (B(2)pin(2)) under mild conditions has been developed. Acetic acid acted as the solvent and the hydrogen source, which has been identified by deuterium experiments. Notably, isomerization-hydroboration of allyl benzene derivatives was observed. As a result, a series of benzyl boronic esters were obtained in moderate to excellent yields with exclusive regioselectivity.
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