期刊
CHEMICAL COMMUNICATIONS
卷 54, 期 10, 页码 1225-1228出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc09250d
关键词
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资金
- National Basic Research Program of China [(973)-2015CB856603]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20000000]
- National Natural Science Foundation of China [20472096, 21372241, 21572052, 20672127, 21421091, 21372250, 21121062, 21302203, 20732008, 21772037, 21772226]
A gold-catalyzed method for the construction of indolizines with eight-membered rings has been developed. The reaction proceeded through a two-fold hydroarylation with indole or pyrrole derivatives containing a 1,6-diyne using a tri(1-adamantyl) phosphine gold complex as the catalyst, affording 1,8-disubstituted indolizines in moderate to good yields in DCE at 80 degrees C. The potential usefulness of these indolizines as blue or green OLEDs has been also disclosed.
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